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A polyamide fibre is defined by BISFA as being "a
fibre composed of linear macromolecules having in the chain recurring
amide linkages, at least 85% of which are joined to aliphatic or cycloaliphatic
units". There are many polyamide fibres made but only two, described
below, are made in significant quantities. The first fibres made from
polyamide polymers were produced in 1938 in the USA and Germany. In the
USA the raw materials, which were used to produce the polymer, were adipic
acid and hexamethylene diamine. Since both chemicals contain 6 carbon
atoms the new polymer was named polyamide 6.6. In Germany caprolactam
was polymerised to produce a different fibre known as polyamide 6.
Production
To produce fibres from the polyamide polymers the molten polymer is pumped
through spinneret holes at a temperature approaching 300 degrees C to
form filaments that are cooled and solidified in a quench air stream.
If filament yarn is being produced the filaments are then oiled and wound
onto cylinders. Polyamide yarns are spun to different orientations depending
upon the use. If a fully oriented yarn (FOY or FDY) is required it is
achieved by having a draw stage on the spinning machine, a process called
spindrawing, or by spinning the yarn at very high speeds. (see annex 3)
If the yarn is to be textured the preferred orientation is partial (POY).
This yarn is then fully drawn and textured in a separate process. If staple
fibres are being produced, very many filaments are bundled together to
form a tow which is subsequently stretched, crimped and cut to the desired
length. In 1999 there were over 3.4 million tonnes of polyamide filament
produced worldwide and over 0.5 million tonnes of polyamide staple. (Chart
5)
Properties and End-Uses
In weaving the main end-use is for outerwear and technical fabrics. In
knitting, stockings and tights and outerwear are both important outlets.
Carpets and ropes and twines are also important sectors. (Chart 6)
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